Coordinative activation of nitrosoarenes

Herberhold, Max; Hill, Anthony F.

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Coordinative activation of nitrosoarenes

Date

1989-03-21

Authors

Herberhold, Max

Hill, Anthony F.

Abstract

Nitrosobenzene, reacts readily with [OsCl(NO)(PPh3)2(L)] (L = C2H4, PPh3) to replace the labile ligand, L, and form of complex [OsCl(NO)(ONPh)(PPh3)2] in which the nitrosoarene ligand is coordinated through both nitrogen and oxygen. The nitrosobenzene complex reacts reversibly with hydrogen chloride to provide a 1 1 adduct, formulated as the divalent osmium hydroxylamino complex [OsCl2{N-OH)Ph}(NO)(PPh3)2].

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https://dspace-test.anu.edu.au/handle/1885/733729361

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DevOps Pure Testing

Source

Journal of Organometallic Chemistry

Type

Article

DOI

10.1016/0022-328X(89)87123-2

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Coordinative activation of nitrosoarenes

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