Metallathiirenes. 5.1 Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

Foreman, Mark R.St J.; Hill, Anthony F.; Tshabang, Never; White, Andrew J.P.; Williams, David J.

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Metallathiirenes. 5.1 Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

Date

2003-12-22

Authors

Foreman, Mark R.St J.

Abstract

The synthesis of the molybdenum thiocarbamoyl complexes was presented. The complexes were obtained from the reactions of [Mo(η2-SCNMe 2)Cl(CO)2(tmeda)] and Na[HnB(mt) 4-n] or via reactions of the salts Na[Mo(CO)2+n{H nB(mt)4-n}] with Me2NCSCl. For n=2, the complex displayed agostic B-H-Mo coordination in solution and the solid state. The B-H hydrogen atoms, were located and refined freely to provide B-H(1) and Mo-H(1) separations of 1.22(4) and 1.92(4) Å respectively.

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https://dspace-test.anu.edu.au/handle/1885/733713674

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DevOps Pure Testing

Source

Organometallics

Type

Article

DOI

10.1021/om030584o

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Metallathiirenes. 5.1 Bis- and Tris(methimazolyl)borato Thiocarbamoyl Complexes of Molybdenum(II)

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