On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)

Terrett, Richard; Cavigliasso, German; Stranger, Robert; Yates, Brian F

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On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)

Date

2011

Authors

Terrett, Richard

Cavigliasso, German

Stranger, Robert

Yates, Brian F

Publisher

Royal Society of Chemistry

Abstract

The calix[4]arene niobium(iii) complex ([L]Nb-NN-Nb[L] where [L] = p-tert-butylcalix[4]arene), reported to bind N2 in a μ2-linear dimeric capacity and to activate the N2 triple bond to 1.39 Å, corresponding to the longest N2 bond known in the end-on coo

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http://hdl.handle.net/1885/62442

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Open Access Research

Source

Dalton Transactions

Type

Journal article

DOI

10.1039/c1dt11091h

Restricted until

2037-12-31

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On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)

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