A self-consistent study of ion adsorption and discrete charge effects in the electrical double layer

Chan, Derek Y.C.; Mitchell, D. John; Ninham, Barry W.

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A self-consistent study of ion adsorption and discrete charge effects in the electrical double layer

Date

1980

Authors

Chan, Derek Y.C.

Mitchell, D. John

Ninham, Barry W.

Abstract

A self-consistent treatment is given for ion size effects, specific ionic adsorption, and discrete surface charge effects in the electrical double layer at a planar surface. Ionic interactions are considered in the Mean Spherical Approximation and specific adsorption is modelled by the sticky potential of Baxter. Analytic results include the surface charge-surface potential relationship, the adsorption isotherm, and a comparison with the surface dissociation model of Ninham and Parsegian.

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https://dspace-test.anu.edu.au/handle/1885/733731619

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DevOps Pure Testing

Source

Journal of Chemical Physics

Type

Article

DOI

10.1063/1.439750

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A self-consistent study of ion adsorption and discrete charge effects in the electrical double layer

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