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Organometallic Complexes for Nonlinear Optics. 22. Quadratic and Cubic Hyperpolarizabilities of trans -Bis(bidentate phosphine)ruthenium σ-Arylvinylidene and σ-Arylalkynyl Complexes

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Date

2001

Authors

Hurst, Stephanie
Cifuentes, Marie
Morrall, Joseph
Lucas, Nigel
Whittall, Ian
Humphrey, Mark
Asselberghs, Inge
Persoons, Andre Pierre
Samoc, Marek
Luther-Davies, Barry

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The syntheses of trans-[Ru(C=CHR)Cl(pp)2]PF6 (pp = dppm, R = 4-C6H4C≡CPh, 4-C6H4-CHO, 4,4′-C6H4C≡CC6H4 NO2, (E)-4,4′-C6H4 CH=CHC6H4NO2, 4,4′,4″-C≡CC6H4C≡CC6 H4- C≡CC6H4NO2; pp = dppe, R = 4-C6H4CHO, (E)-4,4′-C6H4CH=CHC6H4 NO2) and tran

Description

Keywords

Keywords: Arylalkynyl complexes; Arylvinylidene; Bisbidentate phosphine ruthenium; Hyperpolarizabilities; Cyclic voltammetry; Electrochemistry; Light absorption; Nonlinear optics; Oxidation; Rayleigh scattering; Reduction; Ruthenium compounds; Synthesis (chemical);

Citation

URI

http://hdl.handle.net/1885/92978

Collections

Open Access Research

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om0101700

Restricted until

2037-12-31

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Description
01_Hurst_Organometallic_Complexes_for_2001.pdf (191.76 KB)

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