C-H activation (γ-deprotonation) of a Sm(III) bis(trimethylsilyl) amide complex via macrocyclic stabilisation of the sodium counter ion
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The γ-deprotonation of a samarium(III) bis(trimethylsilyl)amide complex derived from a dimetallated trans-dioxaporphyrinogen has been achieved through stabilisation of the counter cation within the macrocyclic cavity.
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Chemical Communications