Test environment running 7.6.6

Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic

Thumbnail Image

Date

2013

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70 °C followed by a gradual mass loss until the whole structure collapsed at about 400 °C.

Description

Keywords

Lanthanide, Metal organic framework, Thermal, X-ray crystallography

Citation

URI

https://dspace-test.anu.edu.au/handle/1885/733739581

Collections

DevOps Pure Testing

Source

Type

Conference contribution

Book Title

Entity type

Access Statement

License Rights

DOI

10.1063/1.4858762

Restricted until

DSpace software copyright © 2002-2026 LYRASIS