Highly diastereoselective radical reactions of substituted methylideneimidazolidinones and related systems

Adamson, George; Beckwith, Athelstan (Athel); Chai, Christina

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Highly diastereoselective radical reactions of substituted methylideneimidazolidinones and related systems

Date

2004

Authors

Adamson, George

Beckwith, Athelstan (Athel)

Chai, Christina

Publisher

CSIRO Publishing

Abstract

Stannane-mediated radical addition to tnethylideneimidazolidinones occurs with good to excellent diastereo-selectivity. The stereochemical outcome of addition is highly dependent on the nature of the NI substituent on the imidazolidinone ring.