Synthesis and X-ray crystal structure of a cyclic hemiorthoester

Jackson, Kerrie; Banwell, Martin; Willis, Anthony

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Synthesis and X-ray crystal structure of a cyclic hemiorthoester

Date

2006

Authors

Jackson, Kerrie

Banwell, Martin

Willis, Anthony

Publisher

ARKAT Foundation

Abstract

Treatment of the acetonides 1 and 2 with trifluoroacetic acid in the presence of small amounts of water affords, in good yield, the corresponding cyclic hemiorthoesters 5 and 6, respectively. A single crystal X-ray analysis of compound 5 has been carried

Keywords

Keywords: Acetonides; Anomeric effect; Hemiorthoester; Hydrolysis; Trifluoromethyl group

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http://hdl.handle.net/1885/85043

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Open Access Research

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ARKIVOC

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Journal article

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2037-12-31

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Synthesis and X-ray crystal structure of a cyclic hemiorthoester

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