Synthesis of the 12-hydroxy glbberellins GA31,GA69 and GA70

Chu, Alex; Mander, Lewis N.

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Synthesis of the 12-hydroxy glbberellins GA31,GA69 and GA70

Date

1988

Authors

Chu, Alex

Mander, Lewis N.

Abstract

Gibberellic acid has been transformed into the methyl esters of the 12-hydroxy gibberellins GA31,GA69 and GA70. The key steps in the conversions are the transannular abstraction of H(12/gb) by treatment of a 16α-bromo-17-carbinol with lead tetra-acetate and the reductive fission of the resulting 12β,17-ether.

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https://dspace-test.anu.edu.au/handle/1885/733725974

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DevOps Pure Testing

Source

Tetrahedron Letters

Type

Article

DOI

10.1016/0040-4039(88)85271-7

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Cultural advice

Synthesis of the 12-hydroxy glbberellins GA31,GA69 and GA70

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