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Polymethylsqualanes from Botryococcus braunii in lacustrine sediments and crude oils

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A novel hydrocarbon 3,7,18,22-tetramethylsqualane has been identified in extracts from the Maniguin-2 well on Maniguin Island, Philippines, the Duri oil from Sumatra, Indonesia and the Maoming Oil Shale from China. A related hydrocarbon, tentatively assigned the structure 3,7,11,14-tetramethylsqualane, occurs in the Maniguin samples. Like C34 botryococcane, the tetramethylsqualanes are unusually enriched in 13C compared to co-occuring n-alkanes and C16-20 acyclic isoprenoids. Polymethylsqualanes extend the range of distinctive hydrocarbons produced by Botryo- coccus braunii and its fossil counterparts.

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Organic Geochemistry

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